• 专利附录
  • 专利说明
  • 权利要求
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    • 专利摘要:
    system and method for measuring a level of a mixture and method for determining a composition" The subject matter disclosed herein generally relates to sensors, and more particularly to level sensors for determining the interface level of a fluid composition of multiphase. it is a system that includes a container system for a fluid, a sampling assembly and a resonant sensor system (11) coupled to the sampling assembly. the resonant sensor system (11) may include a subsystem that detects a series of signals from a resonant sensor system (11) at a plurality of locations on the container. the resonant sensor system (11) may also include a subsystem that converts the series of signals into complex impedance spectrum values for the plurality of locations and stores the complex impedance spectrum values and frequency values. a subsystem determines a fluid phase inversion point from the complex impedance spectrum values.
    公开号:BR112015006097B1
    申请号:R112015006097
    申请日:2013-09-10
    公开日:2020-04-14
    发明作者:William Guy Morris；Cheryl Margaret Surman；Jon Albert Dieringer；Radislav A. Potyrailo；Steven Go；William Chester Platt
    申请人:Bl Technologies, Inc.；
    IPC主号:
    专利说明:

    "SYSTEM AND METHOD FOR MEASURING A MIXTURE LEVEL AND METHOD FOR DETERMINING A COMPOSITION"
    Field of the Invention [001] The matter disclosed in this document generally relates to sensors and, more particularly, to level sensors for determining the interface level of a multiphase fluid composition.
    Background of the Invention [002] The measurement of the composition of emulsions and the interface level of immiscible fluids are important in many applications. For example, it is important to characterize emulsions in oil field management. The measurement of water and oil content of emulsions from individual oil wells can vary over the life of an oil field and can indicate the overall health of a field. In the case of injection wells, it is important to control water quality to reduce hydrate formation and corrosion. Characterizing the composition of the oil and water mixture (for example, measuring the relative proportions of oil and water in the mixture) helps the operator to improve productivity and well capacity. The information obtained is also useful for reducing counter well pressure, flow line size and complexity and thermal insulation requirements.
    [003] The characterization of emulsions is also important in the operation of systems that contain fluids in a container (container systems), such as fluid processing systems. Container systems can include storage tanks, reactors, separators and desalinators. Container systems are used in many industries and processes, such as the oil and gas, pharmaceutical, food processing industries, among others. For example, the separation of water from crude oil is important to establish an oil and gas production course. The crude oil that leaves the wellhead is both sulfurous (contains
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    2/31 sulfide hydrogen) and wet (contains water). The crude oil that comes out of the wellhead needs to be processed and treated to be economically viable for storage, processing and export. One way to treat crude oil is through the use of a separator. Most separators are gravity driven and use the density differences between individual fluid phases of oil, water, gas and solids to perform the separation. The identification of the interface levels of these layers is important to control the separation process. Another fluid processing system in which the characterization of emulsions and measurement of the interface level is important is a desalinizer. Desalinizers are used in a refinery to control downstream overhead corrosion. In a desalinator, water and crude oil are mixed, inorganic salts are extracted from the water and the water is then separated and removed.
    [004] Finally, it is important to accurately characterize the water and salinity in the crude oil itself at various stages of the product's life from a cost point of view. Oil is a valuable asset and underestimating the water content in a typical tanker cargo can have significant cost consequences.
    [005] Wastewater management is another application in which the measurement and characterization of emulsion emulsion is important. Large amounts of oily waste water are generated in the oil industry both from recovery and refining. A key factor in controlling oil discharge concentrations in wastewater is improved instrumentation to monitor the oil content of emulsions.
    [006] Many types of level and interface instruments have been considered over the years and a subseries of them have been marketed. Among them are gamma ray sensors, guided wave sensors, magnetostrictive sensors, microwave sensors,
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    3/31 ultrasonic sensors, single plate capacitance / admittance sensors, segmented capacitance sensors, inductive sensors and computed tomography sensors. Each of the sensors has advantages and disadvantages. Some of the sensors are extremely expensive for many users. Some of the sensors may require a cooling jacket to run at operating temperatures (above 125 ° C). Some interface instruments require a clear interface to function, which can be problematic when working with diffuse emulsions. Some are susceptible to fouling. Other sensors are not able to provide a profile of the tank, but instead are able to monitor different points in the desalination process. Systems using electrodes are susceptible to electrode short circuits in high salinity applications and susceptible to scaling. Finally, many of these systems are complex and make deployment difficult.
    [007] Some existing sensor systems used individual capacitive elements to measure fluid levels. A key limitation of these sensor systems is their inability to simultaneously quantify various components in the liquid. Capacitance methods have been used to measure a liquid's dielectric constant using electrodes designed specifically for capacitance measurements. These designs are limited by the need for separate types of electrodes for capacitance measurements and for conductivity measurements. Inductor and capacitor circuits have also been used to monitor the fluid level in a container using an electromagnetic resonator in which the change in capacitance was related to the fluid level and the type of fluid. However, there was a consensus among technicians on the subject that filling the resonator with a liquid increased the uncertainties and noise in measurements by about an order of magnitude,
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    4/31 as compared to the values in a non-conductive fluid, such as in air. However, these methods do not provide accurate measurements of individual analyte concentrations within the limits of the minimum and maximum concentration of the same in the mixture.
    [008] With existing sensor systems, no other system is capable of delivering a combination of low cost, high sensitivity, favorable signal-to-noise ratio, high selectivity, high precision and high data acquisition speeds. In addition, no existing system has been described as having the capacity to characterize or precisely quantify mixtures of fluids in which one of the fluids is in a low concentration (ie, maximum and minimum limits).
    Description of the Invention [009] The disclosure provides a technical solution to the expense, reliability and accuracy problems of existing level sensor systems. An electrically resonant transducer (resonant transducer) provides a combination of low cost, high sensitivity, favorable signal-to-noise ratio, high selectivity, high accuracy and high data acquisition speeds. The resonant transducer is incorporated in a resistant sensor without the need for a clear interface. The solution also provides a sensor that is less susceptible to fouling, particularly in applications involving emulsions.
    [010] In accordance with an exemplary non-limiting embodiment, the disclosure refers to a sensor that has a resonant transducer configured to determine an emulsion composition and includes a sampling set and an impedance analyzer.
    [011] In another embodiment, the disclosure refers to a system that includes a fluid processing system, a fluid sampling set and a resonant sensor system coupled to the set of
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    5/31 fluid sampling.
    [012] In another embodiment, the disclosure refers to a method for measuring a level of a mixture of fluids in a container. The method includes the steps of detecting a signal from a resonant sensor system at a plurality of locations in the container; converting each signal to values of the complex impedance spectrum for the plurality of locations; store the values of the complex impedance spectrum and the frequency values and determine a point of inversion of the fluid phase from the values of the complex impedance spectrum.
    [013] In another embodiment, the disclosure refers to a method for determining a composition of a mixture of oil and water in a container. The method includes the step of determining values of the complex impedance spectrum of the oil and water mixture as a function of a height in the vessel with a resonant transducer. The method also includes the step of determining a fluid phase inversion point from the values of the complex impedance spectrum; apply an oil phase model to complex impedance spectrum values and conductivity values above the fluid phase inversion point and apply a water phase model to complex impedance spectrum values below the phase inversion point of fluid.
    [014] In another embodiment, the disclosure refers to a sensor that comprises a resonant transducer configured to simultaneously determine the concentration of a first and a second component of an emulsion.
    [015] In another embodiment, the disclosure refers to a sensor that has a resonant transducer configured to determine an emulsion composition.
    [016] In another embodiment, the revelation refers to a system of
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    6/31 sensor that has a resonant transducer configured to determine an emulsion composition. The sensor system includes a sampling set and an impedance analyzer.
    [017] In another embodiment, the disclosure refers to a method for determining a composition of a mixture of a first fluid and a second fluid in a container. The determination of the composition is carried out by determining, with a sensor system, a series of complex impedance spectrum values of the mixture of the first fluid and the second fluid as a function of a height in the container. The method includes the step of determining a fluid phase inversion point from the series of complex impedance spectrum values. The method also includes the steps of applying a phase model of the first fluid to the series of complex impedance spectrum values above the reversal point of the fluid phase and applying a phase model of the second fluid to the series of impedance spectrum values. complex below the fluid phase inversion point.
    Brief Description of the Drawings [018] Other features and advantages of the present disclosure will be apparent from the following detailed description of the preferred realization, taken in combination with the accompanying drawings that illustrate, by way of example, the principles of certain aspects of the disclosure.
    [019] Figure 1 is a schematic of a non-limiting realization of a resonant sensor system.
    [020] Figure 2 is a non-limiting illustration of the operation of a resonant transducer.
    [021] Figure 3 is an example of a measured complex impedance spectrum used for multivariate analysis.
    [022] Figure 4 illustrates an embodiment of a two-dimensional resonant transducer.
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    7/31 [023] Figure 5 illustrates an embodiment of a three-dimensional resonant transducer.
    [024] Figure 6 is a schematic electrical diagram of the equivalent circuit of a three-dimensional resonant transducer.
    [025] Figure 7 is a graph that illustrates the Rp response of a resonant transducer to varying mixtures of oil and water.
    [026] Figure 8 is a graph that illustrates the Cp response of a resonant transducer to varying mixtures of oil and water.
    [027] Figure 9 is a side view in partial section of an embodiment of a resonant transducer set.
    [028] Figure 10 is a schematic diagram of an embodiment of a fluid processing system.
    [029] Figure 11 is a schematic diagram of an embodiment of a desalinizer.
    [030] Figure 12 is a schematic diagram of an embodiment of a separator.
    [031] Figure 13 is a graph that illustrates the frequency response (Fp) of a three-dimensional resonant transducer to increasing concentrations of oil in water and water in oil emulsions.
    [032] Figure 14 is a graph that illustrates the frequency response (Fp) of a two-dimensional resonant transducer to increasing concentrations of oil in water and water in oil emulsions.
    [033] Figure 15 is a flow chart of an embodiment of a method for determining the composition of a mixture of oil and water as a function of height.
    [034] Figure 16 is a graph that illustrates the data used to determine a point and conductivity of phase inversion of fluid.
    [035] Figure 17 is a graph that illustrates the results of a
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    8/31 analysis of the experimental data of an implementation of a resonant sensor system.
    [036] Figure 18 is a graph that illustrates test results from a resonant sensor system in a simulated desalinizer.
    [037] Figure 19 is a realization of a display of a data report from a resonant sensor system.
    [038] Figure 20 is a flow chart and an embodiment of a method for determining the level of a fluid in a container.
    [039] Figure 21 is a block diagram of a representative non-limiting embodiment of a processor system for use in a resonant sensor system.
    Description of Embodiments of the Invention [040] As discussed in detail below, the embodiments of the present invention provide low-cost systems for reliably and precisely measuring the fluid level in a fluid processing vessel. A resonant sensor system provides effective and accurate measurement of the level of the transition or emulsion layer through the use of a resonant transducer such as a multivariable resonant transducer with inductor-capacitor-resistor (LCR) structure and the application of multivariate analysis for data applied to the transducer signals. The resonant sensor system also provides the ability to determine the composition of mixtures of oil and water, mixtures of oil and water and, where applicable, the emulsion layer.
    [041] The resonant transducer includes a resonant circuit and a magnet coil. The electrical response of the resonant transducer immersed in a fluid is translated as simultaneous changes to various parameters. These parameters can include a complex impedance response, peak resonance position, peak width, peak height and symmetry of
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    9/31 peak of the sensor antenna impedance response, magnitude of the real part of the impedance, resonant frequency of the imaginary part of the impedance, anti-resonant frequency of the imaginary part of the impedance, zero reactance frequency, phase angle and magnitude of impedance, and others, as described in the definition of the term spectral sensor parameters. These spectral parameters can change, depending on the dielectric properties of the surrounding fluids. Typical configurations for a resonant transducer can include an LCR resonant circuit and an antenna. The resonant transducer can operate with a magnet coil connected to the detector reader (impedance analyzer), where the magnet coil provides excitation of the transducer and detection of the transducer response. The resonant transducer can also operate when excitation of the transducer and the detection transducer response is performed when the transducer is connected directly to the detector reader (impedance analyzer).
    [042] A resonant transducer offers a combination of high sensitivity, favorable signal-to-noise ratio, high selectivity, high precision and high data acquisition speeds in a resistant sensor without the need for optical transparency of the analyzed fluid and flow path measuring Instead of conventional impedance spectroscopy that scans across a wide frequency range (from a fraction of Hz to tens of MHz or GHz), a resonant transducer is used to acquire a spectrum quickly and with a high signal for noise across only from a narrow frequency range. The pickup capacity is increased by placing the pickup region between the electrodes that constitute a resonant circuit. As implanted in a fluid processing system, such as a desalinizer or separator, the resonant sensor system can include a sampling set and a resonant transducer coupled to the fluid sampling set. The system of
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    10/31 resonant sensor implements a method to measure the level of a mixture of fluids in a container and can also implement a method to determine the composition of a mixture of oil and water in a container. Resonant transducers are capable of precisely quantifying individual analytes at their maximum and minimum limits. The resonant sensor system can determine the composition of fluid mixtures even when one of the fluids is in a low concentration.
    [043] A non-limiting example of fluid processing systems includes reactors, chemical reactors, biological reactors, storage containers, containers and others known in the art.
    [044] A schematic of an embodiment of a resonant sensor system 11 is illustrated in Figure 1. The resonant sensor system 11 includes a resonant transducer 12, a sampling set 13 and an impedance analyzer (analyzer 15). The analyzer 15 is coupled to a processor 16, such as a microcomputer. The data received from the analyzer 15 is processed using multivariate analysis and the output can be provided through a user interface 17. The analyzer 15 can be an impedance analyzer that measures both the amplitude property and the phase property and correlates the changes in impedance to the physical parameters of interest. The analyzer 15 scans the frequencies through the range of interest (that is, the resonant frequency range of the LCR circuit) and collects the impedance response from the resonant transducer 12.
    [045] As shown in Figure 2, the resonant transducer 12 includes an antenna 20 arranged on a substrate 22. The resonant transducer can be separated from the environment with a dielectric layer 21. In some embodiments, the thickness of the dielectric layer 21 can vary by a range from 2 nm to 50 cm, more specifically, from 5 nm to 20 cm and, even more specifically, from 10 nm to 10 cm. In some applications, the transducer
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    Resonant 11/31 12 may include a capture film arranged on the transducer. In response to environmental parameters, an electromagnetic field 23 can be generated at the antenna 20 that extends outward from the plane of the resonant transducer 12. The electromagnetic field 23 can be affected by the dielectric property of an environment that provides the opportunity for measurements of physical parameters. The resonant transducer 12 responds to changes in the complex permissiveness of the environment. The real part of the complex permissiveness of the fluid is called the dielectric constant. The imaginary part of the complex fluid permissiveness is called the dielectric loss factor. The imaginary part of the complex permissiveness of the fluid is directly proportional to the conductivity of the fluid.
    [046] Fluid measurements can be performed using a protective layer that separates the conduction medium from the antenna 20. The response of the resonant transducer 12 to the composition of the fluids may involve changes in the dielectric and dimensional properties of the resonant transducer 12. These changes are related to the analyzed environment that interacts with the resonant transducer 12. The fluid-induced changes in the resonant transducer 12 affect the complex impedance of the antenna circuit through changes in capacitance and material resistance between the antenna turns.
    [047] For selective fluid characterization using a resonant transducer 12, the complex impedance spectra of the sensor antenna 20 are measured, as shown in Figure 3. At least three emulsion impedance spec data data are measured. Best results can be achieved when at least five data points of the emulsion impedance spectra are measured. Non-limiting examples of the number of measured data points are 8, 16, 32, 64, 101, 128, 201, 256, 501, 512, 901, 1024, 2048 data points. The spectra
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    12/31 can be measured as a real part of impedance spectra or an imaginary part of impedance spectra or both parts of impedance spectra. Non-limiting examples of LCR resonant circuit parameters include impedance spectrum, real part of the impedance spectrum, imaginary part of the impedance spectrum, both the real part and the imaginary part of the impedance spectrum, frequency of the maximum of the real part of the complex impedance (Fp), magnitude of the real part of the complex impedance (Zp), resonant frequency (F1) and magnitude of the same (Z1) of the imaginary part of the complex impedance, and anti-resonant frequency (F2) and the magnitude of the same (Z2) of the part complex impedance.
    [048] Additional parameters can be extracted from the equivalent circuit response of the resonant transducer 12. Non-limiting examples of the resonant circuit parameters may include resonance quality factor, zero reactance frequency, phase angle and impedance magnitude of the circuit response of resonance of the resonant transducer 12. The multivariate analysis applied reduces the dimensionality of the multivariate response of the resonant transducer 12 to a single data point in multidimensional space for selective quantification of different environmental parameters of interest. Non-limiting examples of multivariate analysis tools are canonical correlation analysis, regression analysis, non-linear regression analysis, principal component analysis, discriminant function analysis, multidimensional scaling, linear discriminant analysis, logical regression and / or neural network analysis . By applying multivariate analysis of the complete complex impedance spectra or the calculated spectral parameters, the quantitation of the analytes and mixtures of them with interferences can be performed with a resonant transducer 12. In addition to measurements of the parameters of complex impedance spectra, it is possible measure other spectral parameters related to impedance spectra
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    Complex 13/31. Examples include, but are not limited to, S parameters (diffusion parameters) and Y parameters (admittance parameters). Using multivariate analysis of sensor data, it is possible to achieve simultaneous quantification of multiple parameters of interest with a single resonant transducer 12.
    [049] A resonant transducer 12 can be defined as one-dimensional, two-dimensional or three-dimensional. A one-dimensional resonant transducer 12 can include two wires in which one wire is disposed adjacent to the other wire and can include additional components.
    [050] A two-dimensional resonant transducer 25 is shown in Figure 4 that has a transducer antenna 27. The two-dimensional resonant transducer 25 is a resonant circuit that includes an LCR circuit. In some embodiments, the two-dimensional resonant transducer 25 can be coated with a pick-up film 21 applied to the pick-up region between the electrodes. The transducer antenna 27 may be in the form of a coiled wire arranged in a plane. The two-dimensional resonant transducer 25 can be wired or wireless. In some embodiments, the two-dimensional resonant transducer 25 may also include an IC 29 chip coupled to the transducer antenna 27. The IC 29 chip can store manufacturing, user, calibration and / or other data. The IC 29 chip is an integrated circuit device and includes a set of RF signal modulation circuits that can be manufactured using a complementary metal-oxide semiconductor (CMOS) process and a non-volatile memory. The RF signal modulation circuitry components can include a diode rectifier, a power supply voltage control, a modulator, a demodulator, the signal generator and other components.
    [051] The capture is carried out by monitoring the changes in the complex impedance spectrum of the two-dimensional resonant transducer 25, as probed by the electromagnetic field 23 generated in the
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    14/31 transducer antenna 27. The electromagnetic field 23 generated in the transducer antenna 27 extends outside the plane of the two-dimensional resonant transducer 25 and is affected by the dielectric property of the environment, providing the opportunity for measurements of physical, chemical and biological parameters .
    [052] A three-dimensional resonant transducer 31 is shown in Figure 5. The three-dimensional resonant transducer 31 includes an upper winding 33 and a lower winding 35 coupled to a capacitor 37. The upper winding 33 is packaged around an upper portion of a cell sample 39 and the bottom winding 35 is packaged around a lower portion of the sample cell 39. The sample cell 39 can be, for example, made of a fouling resistant material, such as Polytetrafluoroethylene (PTFE), a fluoropolymer synthetic tetrafluoroethylene.
    [053] The three-dimensional resonant transducer 31 uses mutual inductance of the upper winding 33 to capture the lower winding 35. An equivalent circuit 41 is illustrated in Figure 6, including a current source 43, resistor R0 45, capacitor C0 47 and inductor L0 49 Equivalent circuit 41 also includes inductor L1 51, resistor R1 53 and capacitor C1 55. The circuit also includes capacitor Cp 57 and resistor Rp 59. The circled portion of equivalent circuit 41 shows a sensitive portion 61 that is sensitive to fluid properties surrounding test. A typical Rp response and Cp response of a resonant transducer 12 to varying mixtures of oil and water are shown in Figures 7 and 8, respectively.
    [054] The three-dimensional resonant transducer 31 can be shielded, as shown in Figure 9. A resonant transducer set 63 includes a radio frequency absorber (RF absorber layer 67) surrounding the sampling cell 39, the upper winding 33 and the
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    15/31 bottom winding 35. A spacer 69 can be supplied surrounded by a metal shield 71. Metal shield 71 is optional and is not part of transducer 31. Metal shield 71 allows operation inside or near piping and metal objects, reduces noise and creates a stable environment so that any changes in the sensor response are directly due to changes in the test fluid. In order to successfully encapsulate the sensor in a metal shield 71, the RF absorbing layer 67 can be placed between the sensor and the metal shield 71. This prevents the RF field from interacting with the metal and cooling the response of the sensor. The metal shield 71 can be packed with a cover 73 of suitable material. The RF 67 absorber layer can absorb electromagnetic radiation in different frequency ranges with non-limiting examples in frequency ranges in kilohertz, mega-hertz, giga-hertz, terahertz depending on the operating frequency of the transducer 31 and the sources of interference power . The absorbing layer 67 can be a combination of individual layers for particular frequency ranges, so that the combinations of these individual layers provide a broader spectral range of shielding.
    [055] The encrustation of the resonant sensor system 11 can be reduced by providing the resonant transducer 12 with a geometry that allows the resonant transducer 12 to probe the environment around the sample depth perpendicular to the transducer that is in a range of 0, 1 mm to 1000 mm. Signal processing of the complex impedance spectrum reduces the effects of fouling on the sample depth.
    [056] As shown in Figure 10, the resonant sensor system 11 can be used to determine the level and composition of fluids in a fluid processing system 111. The fluid processing system 111 includes a container 113 with an assembly in
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    16/31 sampling 115 and a resonant sensor system 11. The resonant sensor system 11 includes at least one resonant transducer 12 coupled to the sampling set 115. The resonant sensor system 11 also includes an analyzer 15 and a processor 16.
    [057] In operation, a normally immiscible combination of fluids enters the container through a crude fluid inlet 123. The combination of fluids may include a first fluid and a second fluid normally immiscible with the first fluid. As the fluid combination is processed, the fluid combination is separated into a first fluid layer 117 and a second fluid layer 119. Between the first fluid layer 117 and the second fluid layer 119 there may be a layer emulsion 121. After processing, a first fluid can be extracted via the first fluid outlet 125 and a second fluid can be extracted via the second fluid outlet 127. The resonant sensor system 11 is used to measure the level of the first fluid layer 117, the second fluid layer 119 and the rag layer 121. The resonant sensor system 11 can also be used to characterize the content of the first fluid layer 117, the second fluid layer 119 and the emulsion layer 121.
    [058] An embodiment of a fluid processing system 111 is a desalinizer 141 illustrated in Figure 11. Desalinizer 141 includes a desalinizer container 143. Crude oil enters desalinator 141 through the admission of crude oil 145 is mixed with water from the water inlet 147. The combination of crude oil and water flows through the mixing valve 149 and into the desalination container 143. Desalination 141 includes a treated oil outlet 151 and a waste water outlet 153. They are arranged inside the container desalinizer 143 an oil collector 155 and a water collector 157. Transformer 159 and Transformer 161
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    17/31 supply electricity to the upper electrical network 163 and the lower electrical network 165. Emulsion distributors 167 are arranged between the upper electrical network 163 and the lower electrical network 165.
    [059] In operation, the crude oil mixed with water enters the desalination container 143 and the two fluids are mixed and distributed by emulsion distributors 167, thereby forming an emulsion. The emulsion is kept between the upper electrical network 163 and the lower electrical network 165. Water containing salt is separated from the oil / water mixture by passing through the upper electrical network 163 and the lower electrical network 165 and falls towards the bottom of the 143 m desalination container that is collected as waste water.
    [060] The control of the level of the emulsion layer and the characterization of the contents of the oil-in-water and water-in-oil emulsions is important in the operation of the desalinizer 141. The determination of the level of the emulsion layer can be carried out using a sampling set, such as a set of test tubing 169 coupled to the desalination container 143 and which has at least one resonant transducer 12 disposed in the outlet conduit of test tubing 172. The resonant transducer 12 can be coupled to a collection component 173. In operation, the resonant transducer 12 is used to measure the water and oil level and to allow operators to control the process. The test tubing assembly 169 may be a plurality of open pipes at one end inside the desalination container 143 with an open end permanently positioned at the desired vertical position or level in the desalination container 143 for taking samples of liquid at that level. Generally, there are a plurality of sample pipes in a processing vessel, each with its own sample valve, with the open end of each pipe in a different vertical position inside.
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    18/31 of the unit, so that liquid samples can be taken from a plurality of fixed vertical positions on the unit. Another approach for measuring the level of the emulsion layer is to use an articulated arm sample tester. An articulated-arm sample tester is a pipe with an open end inside the desalination container 143, typically connected to a sampling valve outside the unit. It includes a set used to change the vertical position of the open end of the angled pipe in desalinizer 141, rotating it so that liquid samples can be taken (or sampled) from any desired vertical position.
    [061] Another method for measuring the oil and water level is to arrange at least one resonant transducer 12 on an immersion rod 175. An immersion rod 175 can be a rod with a resonant transducer 12 that is inserted into a desalination container 143 Measurements are made at several levels. Alternatively, the dip stick 175 can be a stationary rod that has a plurality of multiplexed resonant transducers 12. Resonant transducer 12 can be coupled to a data collection component 179 that collects data from the various readings for further processing.
    [062] Another embodiment of a fluid processing system 111 is a separator 191 illustrated in Figure 12. Separator 191 includes a container separator 193 that has an inlet conduit 195 for crude oil. The crude oil flowing from the intake duct 195 impacts an inlet diverter 197. The impact of crude oil on the inlet diverter 197 causes particles of water to begin to separate from the crude oil. The crude oil flows into the processing chamber 199 where it is separated into a water layer 201 and an oil layer 203. The crude oil is transported to the processing chamber 199 below the oil / water interface 204. This forces the
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    19/31 mixture of oil and water inlet with the continuous phase of water at the bottom of the container and causes it to rise through the oil / water interface 204, thereby promoting the precipitation of water droplets that are entrained in the oil . The water settles at the bottom while the oil rises to the top. The oil scum is removed through a dam 205 where it is collected in the oil chamber 207. Water can be removed from the system through a water outlet 209 which is controlled by a 211 water level control valve. similarly, oil can be removed from the system via an oil outlet 213 which is controlled by an oil level control valve 215. The height of the oil / water interface can be detected using a set of test tubing 217 that has at least one resonant transducer 12 disposed in a test tubing outlet conduit 218 and coupled to a data processor 221. Alternatively, a dip rod 223 that has at least one resonant transducer 12 coupled to a Processor 227 can be used to determine the level of the oil / water interface 204. The determined level is used to control the water level control valve 211 to allow water to flow already removed so that the oil / water interface is maintained at the described height.
    [063] The following examples are given by way of illustration only and are not intended to be a limitation of the scope of this disclosure. A model system of heavy mineral oil, tap water and detergent was used to perform statistical tests for various resonant transducer designs 12. The detergent level was kept constant for all mixtures.
    [064] Example 1. In the case of the three-dimensional resonant transducer 31 arranged in a test tubing or in a jointed sampling arm 13, different oil and water compositions were poured into a sample cell with the resonant transducer
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    20/31 three-dimensional 31 wrapped around the outside of the sample cell. Figure 13 shows the test tubing / articulated arm response in terms of Fp (frequency shift from actual impedance) as the oil concentration increases. The calculated limit of detection of the composition of oil in oil-in-water emulsions (Figure 13, part A) is 0.28% and of oil in water-in-oil emulsions (Figure 13, part B) is 0.58% .
    [065] Example 2. In the case of the two-dimensional resonant transducer 25, the two-dimensional resonant transducer 25 was immersed in different oil and water compositions. Figure 14 shows the response of a two-dimensional resonant transducer 25 (circular by 2 cm) in terms of Fp (frequency shift of the real impedance), as the oil concentration increases. The calculated limit of detection of the composition of oil in oil-in-water emulsions (Figure 14, part A) is 0.089% and of oil in water-in-oil emulsions (Figure 14, part B) is 0.044%. This example illustrates that small concentrations of a fluid mixed with large concentrations of another fluid can be measured with a high degree of accuracy.
    [066] Example 3. The model system was located with 250 ml of mineral oil and treated with a detergent in a concentration of 1 drop every 50 ml (5 drops). The mineral oil was stirred and injected through the sensor and the impedance spectra are recorded. Small additions of water were added with constant salinity and with the same detergent treatment. After the volume of water exceeds 66% or 500 ml of water, the system was cleaned and the experiment is repeated with water of different salinities. The multivariate response of the two-dimensional resonant transducer 25 was sensitive to changes in composition and conductivity at all levels in the model system test vessel. Although the effect of conductivity and composition is somewhat twisted, the fact that the sensor monitors a
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    21/31 composition gradient allows the data analysis procedure to distort these effects.
    [067] Figure 15 is a generalized process diagram that illustrates a 261 method for determining the composition of a mixture of oil and water as a function of height.
    [068] In step 263, data (a series of LCR resonant circuit parameters) is collected as a function of height from top to bottom (in the laboratory this is simulated by starting with 100% oil and gradually adding water ).
    [069] In step 265, the water conductivity using calibration is determined. At 100% water, the multivariate response is compared to a calibration for water conductivity.
    [070] In step 267, the fluid phase inversion point is determined using Z parameters.
    [071] In step 269, Z parameters are combined with conductivity and fluid phase data.
    [072] In step 271, an oil phase model is applied. The oil phase model is a series of values that correlate measured frequency values, impedance values and conductivity values to the oil content in a mixture of oil and water.
    [073] In step 273, a water phase model is applied. The water phase model is a series of values that correlate measured frequency values, impedance values and conductivity values to the water content in a mixture of water and oil.
    [074] In step 275, the composition as a height function is determined using the fluid and conductivity phase inversion point as admission parameters in the multivariate analysis and a report is generated.
    Petition 870200003582, of 01/09/2020, p. 33/85
    22/31 [075] Figure 16 shows the gross impedance (Zp) vs. frequency data (Fp) for a profile containing 0 to 66% water from right to left. At approximately 8.12 MHz, the water content is high enough (~ 25%) to induce a reversal from oil fluid phase to continuous water phase. This is apparent from the drastic change in Zp due to the increased conductivity of the test fluid in continuous water phase. A continuous oil phase model is applied to any data points to the right of the fluid phase inversion and a water model to the left. Additionally, a calibration is applied to the end point to determine the conductivity of the water, which in this case was 2.78 mS / cm.
    [076] Figure 17 shows that the results of an analysis of the experiment data from a realization of a three-dimensional resonant sensor system illustrated the correlation between the actual and predicted oil in water and water in oil values and errors forecasting residuals based on the model developed. Part A of the graph plots the actual and predicted oil in water values. Part B of the graph plots the actual and predicted water in oil values. In part A, the data points were modeled separately from the data points in part B (continuous water phase). Parts C and D of the graphs plot the residual error between the actual and predicted oil in water and water in oil values, respectively. Generally, the residual error was less than 0.5% when the actual percentage of oil is between 0% to 60%. The residual error was less than 0.04% when the actual percentage of oil is between 70% to 100%. In the fluid phase inversion, the residual error increases up to 10% and the forecasting capacity is difficult due to fluctuations in the composition of the test fluid in the dynamic test equipment. The prediction capability of the sensor will improve in compositions> 66% water with more training data.
    [077] Figure 18 illustrates the results obtained in a
    Petition 870200003582, of 01/09/2020, p. 34/85
    23/31 simulated desalinator. The graph shows a profile developed by plotting the composition as a function of time. To simulate sampling with the use of an articulated arm that is slowly rotated through the emulsion layer, a test equipment was operated, such that the composition of the test fluid was modulated slowly over time by adding small additions of water. .
    [078] Figure 19 is an illustration of the expected reporting level of the sensor data analysis system. The end user will be shown a plot showing a representation of the composition as a function of height in the desalinator, the level of fluid phase inversion and the width of the emulsion layer. On the left are fluid phase indicators (black oil, gray - continuous oil, hatch - continuous water, white - water) that indicate the water / height curve in percentage. The height of the emulsion layer is the sum of the regions of continuous water and continuous oil. The level of detail indicated will allow the desalinator operator to optimize the feed rate of chemicals in the process, provide more detailed feedback on the performance of a fluid processing system, and highlight process disturbances that can cause damage to the process infrastructure downstream.
    [079] A method 281 for measuring the level of a mixture of fluids in a container 113 is illustrated in Figure 20.
    [080] In step 283, method 281 can detect signals (a series of signals) from a resonant sensor system 11 at a plurality of locations in a container. The signals are generated by a resonant transducer 12 immersed in the fluid mixture. The resonant transducer 12 generates a series of transducer signals corresponding to changes in dielectric properties of the resonant transducer 12 and the signals are detected by an analyzer 15.
    Petition 870200003582, of 01/09/2020, p. 35/85
    24/31 [081] In step 285, method 281 can convert the signals into a series of values from the complex impedance spectrum to the plurality of locations. The conversion is performed using multivariate analysis for data.
    [082] In step 287, method 281 can store the values of the complex impedance spectrum.
    [083] In step 289, method 281 can determine whether a sufficient number of locations have been measured.
    [084] In step 291, method 281 can change the resonant transducer 12 being read (or the location of the resonant transducer 12), if an insufficient number of locations has been measured.
    [085] In step 293, method 281 can determine the fluid phase inversion point if a sufficient number of locations have been measured. The fluid phase inversion point is determined from the values of the complex impedance spectrum, identifying a drastic change in the impedance values.
    [086] In step 295, method 281 can assign a value to the interface level based on the fluid phase inversion point.
    [087] Figure 21 is a non-limiting example block diagram of an 810 processor system that can be used to deploy the device and the methods described in this document. As shown in Figure 21, processor system 810 includes a processor 812 that is coupled to an interconnect bus 814. Processor 812 can be any suitable processor, processor unit or microprocessor. Although not shown in Figure 21, the 810 processor system can be a multiprocessor system and can then include one or more additional processors that are identical or similar to the 812 processor and that are coupled, in communication, to the
    Petition 870200003582, of 01/09/2020, p. 36/85
    25/31 interconnection bus 814.
    [088] Processor 812 in Figure 21 is coupled to a chip set 818, which includes a memory controller 820 and an input / output controller (I / O) 822. As is well known, a chip set provides, typically, memory management and I / O functions, as well as a plurality of time markers, general purpose and / or special purpose recorders, etc. which are accessible or used by one or more processors attached to the 818 chip set. The 820 memory controller performs functions that enable the 812 processor (or processors, if there are multiple processors) to access an 824 system memory and a storage memory in bulk 825.
    [089] System memory 824 can include any type of desired volatile and / or non-volatile memory, such as, for example, static random access memory (SRAM), dynamic random access memory (DRAM), flash memory, memory read-only (ROM), etc. Mass storage memory 825 can include any type of desired mass storage device, including hard drives, optical drives, tape storage devices, etc.
    [090] The I / O controller 822 performs functions that enable the 812 processor to communicate with peripheral input / output (I / O) devices 826 and 828 and an 830 network interface via an I / O bus 832 I / O devices 826 and 828 can be any desired type of I / O device, such as, for example, a keyboard, monitor or display, a mouse, etc. I / O devices 826 and 828 can also be the network interface 830 which can be, for example, an Ethernet device, an asynchronous transfer mode (ATM) device, an 802.11 device, a DSL modem, a modem cable, a cellular modem, etc. that allows the 810 processor system to communicate with another processor system. The
    Petition 870200003582, of 01/09/2020, p. 37/85
    26/31 data from analyzer 15 can be communicated to processor 812 via I / O bus 832 using the appropriate bus connectors.
    [091] While the memory controller 820 and I / O controller 822 are depicted in Figure 21 as separate blocks within the 818 chip set, the functions performed by these blocks can be integrated within a single semiconductor circuit or can be deployed using two or more separate integrated circuits.
    [092] Certain achievements include methods, systems and computer program products in any machine-readable medium to implement the functionality described above. Certain achievements can be implemented using an existing computer processor or by a special purpose computer processor incorporated for that or another purpose or by a connected system and / or firmware, for example. Certain achievements include a computer-readable means for porting or having computer-executable instructions or data structures stored on it. Such computer-readable media can be any media available that can be accessed by a general purpose or special purpose computer or by another machine with a processor. By way of example, such computer-readable media may comprise RAM, ROM, PROM, EPROM, EEPROM, Flash, CD-ROM or other optical disk storage, magnetic disk storage or other magnetic storage devices, or any other medium that it can be used to carry or store desired program code in the form of instructions executable by computer or data structures and which can be accessed by a general purpose or special purpose computer or by another machine with a processor. Combinations of the above are also included within the scope of computer-readable medium. Computer executable instructions comprise, for example,
    Petition 870200003582, of 01/09/2020, p. 38/85
    27/31 example, instructions and data that cause a general-purpose, special-purpose computer, or special-purpose processing machines to perform a particular function or group of functions.
    [093] Generally, instructions executable by computer include routines, programs, objects, components, data structures, etc., that perform particular tasks or implant particular types of abstract data. Computer-executable instructions, associated data structures and program modules represent examples of program code for executing steps for certain methods and systems disclosed in this document. The particular sequence of such executable instructions or associated data structures represents examples of corresponding acts to implement the functions described in such steps.
    [094] The achievements of the present disclosure can be practiced in a networked environment that uses logical connections to one or more remote computers that have processors. Logical connections can include a local area network (LAN) and a wide area network (WAN) which are presented here by way of example and not limitation. Such networked environments are commonplace in office and corporate computer networks, intranets and the Internet and can use a wide variety of different communication protocols. Those skilled in the art will find that such network switching environments will typically cover many types of computer system configurations, including personal computers, handheld devices, multiprocessor systems, microprocessor-based or programmable consumer electronics, network PCs, mini computers, similar mainframe computers. Disclosure achievements can also be practiced in distributed computing environments in which tasks are performed by remote or local processing devices that are connected (or by connected links, wireless links
    Petition 870200003582, of 01/09/2020, p. 39/85
    28/31 or by a combination of wireless or connected links) over a communications network. In a distributed computing environment, program modules can be located on both local and remote memory storage devices.
    [095] Monitoring changes in the complex impedance of the circuit and applying chemometric analysis of the impedance spectra allows the composition and continuous phase of mixtures of oil in water and water in oil to be predicted with a standard error of 0.04% at 0 to 30% water and 0.26% in 30 to 100% water.
    [096] Multivariate analysis tools in combination with data-rich impedance spectra allow interference elimination, and transducers designed for maximum penetration depth reduce the impact of fouling. As the depth of penetration of the resonator extends further inward into the fluid volume, the surface fouling becomes less significant.
    [097] The term analyte includes any desired measured environmental parameter.
    [098] The term “environmental parameters is used to refer to measurable environmental variables within or around a monitoring or manufacturing system. Measurable environmental variables comprise at least one of physical, chemical and biological properties and include, but are not limited to, measurement of temperature, pressure, material concentration, conductivity, dielectric property, various dielectric, metallic, chemical or biological particles in the vicinity of the sensor , or in contact with it, ionization radiation dose and light intensity.
    [099] The term fluids includes gases, vapors, liquids and solids.
    [0100] The term interference includes any environmental parameter
    Petition 870200003582, of 01/09/2020, p. 40/85
    29/31 unwanted which undesirably affects the accuracy and precision of measurements with the sensor. The term “interfering” refers to a fluid or an environmental parameter (which includes, but is not limited to, temperature, pressure, light, etc.) that can potentially produce an interference response by the sensor.
    [0101] The term “transducer” means a disposition that converts one form of energy into another.
    [0102] The term "sensor" means a device that measures a physical quantity and converts it into a signal that can be read by an observer or an instrument.
    [0103] The term “multivariate analysis for data” means a mathematical procedure that is used to analyze more than one variable in a sensor response and to provide information about the type of at least one environmental parameter from the sensor's spectral parameters measured and / or for quantitative information on the level of at least one environmental parameter from the measured sensor spectral parameters.
    [0104] The term resonance impedance or “impedance” refers to the sensor frequency response around the sensor resonance from which the “spectral sensor parameters are extracted.
    [0105] The term spectral parameters is used to refer to measurable variables of the sensor response. The sensor response is the impedance spectrum of the resonant transducer 12 resonance sensor circuit. In addition to measuring the impedance spectrum in the form of Z parameters, S parameters and other parameters, the impedance spectrum (both the real part and the imaginary part) can be analyzed simultaneously using several parameters for analysis, such as, the frequency of the maximum of the real part of the impedance (Fp), the magnitude of the real part of the impedance (Zp), the resonant frequency of the imaginary part of the
    Petition 870200003582, of 01/09/2020, p. 41/85
    30/31 impedance (F1) and the anti-resonant frequency of the imaginary part of the impedance (F2), signal magnitude (Z1) in the resonant frequency of the imaginary part of the impedance (F1), signal magnitude (Z2) in the anti-resonant frequency of the imaginary part impedance (F2) and frequency of zero reactance (Fz), frequency at which the imaginary portion of impedance is zero). Other spectral parameters can be measured simultaneously using the entire impedance spectra, for example, resonance quality factor, phase angle and magnitude of impedance. Together, spectral parameters calculated from the impedance spectra, are here called "resources" or "descriptors". The appropriate selection of resources is performed from potential resources that can be calculated from spectra. Multivariable spectral parameters are described in U.S. Patent Application Serial Number 12 / 118,950 entitled “Methods and systems for calibration of RFID sensors”, which is incorporated into this document for reference.
    [0106] The terminology used in this document is only for the purpose of describing particular achievements and is not intended to limit the invention. Where the definition of terms deviates from the commonly used meaning of the term, an applicant intends to use the definitions provided in this document, as long as specifically indicated. The singular forms “one”, “one” and “the (a)” are intended to include the plural forms as well, unless the context clearly indicates otherwise. It will be understood that, although the terms first (a), second (a), etc. can be used to describe various elements, these elements should not be limited by those terms. The terms are used only to distinguish one element from another. The term and / or includes any and all combinations within one or more of the associated listed items. The phrase “coupled to / to” includes direct or indirect coupling.
    Petition 870200003582, of 01/09/2020, p. 42/85
    31/31 [0107] This written description uses examples to reveal the invention, including the best way and also to allow a person skilled in the art to practice the invention, including producing and using any devices or systems and carrying out any built-in methods. The patentable scope of the invention is defined by the claims and may include other examples that occur to those skilled in the art. Such other examples are intended to be within the scope of the claims, if they have structural elements that do not differ from the literal language of the claims or if they include equivalent structural elements.
    权利要求:
    Claims (14)
    [1]
    Claims:
    1. SYSTEM characterized by comprising:
    - a container system for a fluid;
    - a sampling set; and
    - a resonant sensor system (11) comprising at least one electrically resonant transducer coupled to the sampling set, in which the resonant sensor system (11) measures values of real and imaginary parts of impedance spectra associated with the electronically resonant transducer, while next to the fluid, the measured values of the real and imaginary parts of the impedance spectra each being used independently to determine a fluid composition, and where the resonant sensor system (11) is configured to determine a phase inversion point of fluid.
    [2]
    2. SYSTEM, according to claim 1, characterized in that the container system comprises a container system selected from a group consisting of a desalinator (141), a separator (191), a reactor and a storage tank.
    [3]
    3. SYSTEM, according to claim 1, characterized in that the sampling set (13) comprises at least one selected from a group consisting of an immersion rod (175), an articulated arm and a test pipe (169 ).
    [4]
    4. SYSTEM, according to claim 1, characterized in that it additionally comprises a mixture arranged in the container system, the mixture having a first fluid and a second fluid immiscible with the first fluid and in which the resonant sensor system (11) is configured to determine a relative content of the first fluid and the second fluid at a location in the container system.
    [5]
    5. SYSTEM, according to claim 1, characterized
    Petition 870200003582, of 01/09/2020, p. 44/85
    2/4 by the resonant sensor system (11) comprises a subsystem that:
    - detects a series of signals from a resonant sensor system (11) in a plurality of locations in the container system;
    - converts the series of signals into values of a complex impedance spectrum for the plurality of locations;
    - stores the values of the complex impedance spectrum and the frequency values; and
    - determines a fluid phase inversion point from the complex impedance spectrum values.
    [6]
    6. SYSTEM according to claim 4, characterized in that the mixture comprises an emulsion which is at least a water-in-oil emulsion and an oil-in-water emulsion.
    [7]
    7. METHOD FOR MEASURING A LEVEL OF A MIXTURE of fluids in a container, characterized by understanding the steps of:
    - detecting a series of signals from a resonant sensor system (11) in a plurality of locations in the container, wherein the resonant sensor system (11) comprises at least one electrically resonant transducer;
    - convert the series of signals into values of real and imaginary parts of impedance spectra for the plurality of locations;
    - store the values of the real and imaginary parts of the spectra and the frequency values; and
    - determine a point of inversion of the phase of the fluid from the independent values of the real and imaginary parts of the impedance spectra.
    [8]
    8. METHOD, according to claim 7, characterized by the step of converting the series of signals into values of the real and imaginary parts of the impedance spectra, comprising converting the series of
    Petition 870200003582, of 01/09/2020, p. 45/85
    3/4 signals from real and imaginary parts in impedance spectra values using multivariate data analysis.
    [9]
    9. METHOD, according to claim 7, characterized by the step of determining the fluid phase inversion point comprising identifying the fluid phase inversion point from a change in the values of the real and imaginary parts of the impedance spectra .
    [10]
    10. METHOD FOR DETERMINING A COMPOSITION of a mixture of oil and water in a container characterized by comprising the steps of:
    - determine a series of values of complex impedance spectra and conductivity values of the mixture of oil and water as a function of a height in the vessel with an electrically resonant transducer (11), where the series of impedance spectra values and conductivity values include real and imaginary parts of the impedance spectra;
    - determine a fluid phase inversion point from each value independent of the real and imaginary parts of the impedance spectra;
    - apply an oil phase model to the series of complex impedance spectra values and conductivity values above the fluid phase inversion point; and
    - apply a water phase model to the series of complex impedance spectra values and conductivity values below the fluid phase inversion point.
    [11]
    11. METHOD according to claim 10, characterized in that it additionally comprises the step of generating a report that indicates a relative oil and water content and the mixture of oil and water as a function of height in the container.
    Petition 870200003582, of 01/09/2020, p. 46/85
    ΑΙΑ
    [12]
    12. METHOD FOR DETERMINING A COMPOSITION of a mixture of a first fluid and a second fluid in a container characterized by comprising the steps of:
    - determine, with a sensor system, a series of complex impedance spectrum values of the mixture of the first fluid and the second fluid as a function of a height in the vessel, where the series of complex impedance values includes real parts and imaginary impedance spectra;
    - determine a point of inversion of the phase of the fluid from the independent values of the real and imaginary parts of the impedance spectra;
    - apply a phase model of the first fluid to the series of complex impedance spectrum values above the fluid phase inversion point; and
    - apply a phase model of the second fluid to the series of complex impedance spectrum values below the fluid phase inversion point.
    [13]
    13. METHOD, according to claim 12, characterized by the fact that the sensor system is an electrical resonant transducer.
    [14]
    14. METHOD, according to claim 12, characterized by the fact that the first fluid is oil and the second fluid is water.
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    法律状态:
    2018-11-21| B06F| Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]|
    2019-01-02| B25A| Requested transfer of rights approved|Owner name: BL TECHNOLOGIES, INC. (US) |
    2019-10-15| B06U| Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]|
    2020-03-03| B09A| Decision: intention to grant [chapter 9.1 patent gazette]|
    2020-04-14| B16A| Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 10/09/2013, OBSERVADAS AS CONDICOES LEGAIS. |
    优先权:
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    US13/630,739|US9176083B2|2012-09-28|2012-09-28|Systems and methods for measuring an interface level in a multi-phase fluid composition|
    PCT/US2013/058898|WO2014051985A1|2012-09-28|2013-09-10|Systems and methods for measuring an interface level in a multiphase fluid composition|
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